Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for theexo- andendo-Cyclization of Enynes
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Nieto-Oberhuber, Cristina, Munoz-Herranz, Maria, Buñuel, Elena, Nevado, Cristina, Cárdenas, Diego J. and Echavarren, Antonio M. (2004) Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for theexo- andendo-Cyclization of Enynes. Angewandte Chemie-International Edition, 43 (18). pp. 2402-2406. ISSN 1433-7851
Full text not available from this repository. (Request a copy)Abstract
Alkynophilic cationic gold(I) complexes are very active catalysts for reactions of enynes that proceed exclusively through cyclopropyl carbene complexes as intermediates (see scheme). With such catalysts, the first examples of endocyclic skeletal rearrangements under mild conditions have been observed.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry |
Related URLs: | |
Depositing User: | Rachel Smith |
Date Deposited: | 14 Feb 2012 16:14 |
Last Modified: | 25 Jul 2018 06:54 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/37114 |
DOI: | 10.1002/anie.200353207 |
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