Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for theexo- andendo-Cyclization of Enynes

Nieto-Oberhuber, Cristina, Munoz-Herranz, Maria, Buñuel, Elena, Nevado, Cristina, Cárdenas, Diego J. and Echavarren, Antonio M. (2004) Cationic Gold(I) Complexes: Highly Alkynophilic Catalysts for theexo- andendo-Cyclization of Enynes. Angewandte Chemie-International Edition, 43 (18). pp. 2402-2406. ISSN 1433-7851

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Abstract

Alkynophilic cationic gold(I) complexes are very active catalysts for reactions of enynes that proceed exclusively through cyclopropyl carbene complexes as intermediates (see scheme). With such catalysts, the first examples of endocyclic skeletal rearrangements under mild conditions have been observed.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
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Depositing User: Rachel Smith
Date Deposited: 14 Feb 2012 16:14
Last Modified: 25 Jul 2018 06:54
URI: https://ueaeprints.uea.ac.uk/id/eprint/37114
DOI: 10.1002/anie.200353207

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