Non-aqueous iminium salt mediated catalytic asymmetric epoxidation

Bulman Page, Philip C., Buckley, Benjamin R., Barros, David, Blacker, A. John, Heaney, Harry and Marples, Brian A. (2006) Non-aqueous iminium salt mediated catalytic asymmetric epoxidation. Tetrahedron, 62 (28). pp. 6607-6613. ISSN 0040-4020

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Abstract

A range of substituted dihydroisoquinolinium salts has been tested in the catalytic asymmetric epoxidation of simple alkenes using our newly developed non-aqueous conditions employing tetraphenylphosphonium monoperoxysulfate (TPPP) as oxidant, giving ees of up to 97%. (c) 2006 Elsevier Ltd. All rights reserved.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User: Rachel Smith
Date Deposited: 20 Jun 2011 13:53
Last Modified: 24 Oct 2022 01:44
URI: https://ueaeprints.uea.ac.uk/id/eprint/32873
DOI: 10.1016/j.tet.2005.10.084

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