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ToolsBulman Page, Philip C., Heaney, Harry, McGrath, Matthew J., Sampler, Edward P. and Wilkins, Robert F. (2003) Retro-Mannich reactions of 3-alkyl-3,4-dihydro-2H-1,3-benz e oxazines and the synthesis of axially chiral resorcinarenes. Tetrahedron Letters, 44 (14). pp. 2965-2970. ISSN 0040-4039
Full text not available from this repository. (Request a copy)Abstract
Intermediates involved in the conversion of 3-alkyl-3,4-dihydro-2H-1,3-benz[e]oxazines into 2-N,N-dialkylaminomethylphenol derivatives, using morpholine and other high boiling secondary amines, have been identified and characterised. Additional experiments have established the involvement of o-quinone methide intermediates in the retro-Mannich reactions. Axially chiral resorcinarenes have been prepared by utilising the exchange reactions. (C) 2003 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | solvent,resorcinarenes,generation,derivatives,o-quinone methide,axially chiral,heterocycles,o-quinone methides,reactivity,aminol ethers |
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
| Depositing User: | Rachel Smith |
| Date Deposited: | 21 Jun 2011 09:55 |
| Last Modified: | 24 Oct 2022 02:53 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/32847 |
| DOI: | 10.1016/s0040-4039(03)00393-9 |
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