Muon spin relaxation study of Zr(H2PO4)(PO4)center dot 2H(2)O

Clayden, N. J. and Cottrell, S. P. (2006) Muon spin relaxation study of Zr(H2PO4)(PO4)center dot 2H(2)O. Physical Chemistry Chemical Physics, 8 (26). pp. 3094-3098. ISSN 1463-9076

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Abstract

Muon spin relaxation has been used to study the muon dynamics in the layered zirconium phosphate Zr(H2PO4)(PO4) (.) 2H(2)O as a function of temperature. Radiofrequency decoupling was used to establish the origin of the local dipolar field as coupling with 1 H spins. Muons were trapped at two sites, one identified as HMuO and the other consistent with PO-Mu on the basis of their zero-field second moments. Although a small decrease in the local nuclear dipolar field was seen with temperature, the muons remained essentially static over the temperature range 20-300 K.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 14 Jun 2011 15:54
Last Modified: 12 Nov 2018 13:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/32507
DOI: 10.1039/b603913h

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