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McDermott, Michael C., Stephenson, G. Richard 
ORCID: https://orcid.org/0000-0003-1487-9178 and Walkington, Andrew J.
(2007)
Silver-sensitive enantioselectivity in asymmetric Heck reactions.
Synlett (1).
pp. 51-54.
ISSN 0936-5214
Abstract
Amine- and pure Ag(I)-promoted asymmetric Heck cyclisations of 2-iodobut-2-enanilide 1 both gave the oxindole product (R)-(+)-2 in relatively low ee but the partial reduction of the silver salt promoted a substantially more stereocontrolled route to (S)-(-)-2 in a reaction in which the use of Strem Atg(3)PO(4) gave the R-product and Aldrich Ag3PO4 gave the S-product.
| Item Type: | Article |
|---|---|
| Additional Information: | McDermott, Michael C. Stephenson, G. Richard Walkington, Andrew J. |
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) |
| Depositing User: | Rachel Smith |
| Date Deposited: | 08 Jun 2011 10:48 |
| Last Modified: | 24 Oct 2022 01:26 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/32011 |
| DOI: | 10.1055/s-2006-958447 |
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