Muon spin rotation of carbonyl compounds, an exploration of the mechanism of hyperfine interaction

Stride, J. A., Jayasooriya, U. A. and Reid, I. D. (2002) Muon spin rotation of carbonyl compounds, an exploration of the mechanism of hyperfine interaction. The Journal of Physical Chemistry A, 106 (2). pp. 244-250.

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Abstract

The relationship between the muon electron hyperfine coupling constant and the C=O bond stretching frequency of a series of organic carbonyl compounds at 300K has been investigated. A linear relationship is shown to exist between these two properties, but for the aromatic carbonyl compounds only. This observation is shown to be in agreement with the presently accepted hyperconjugative mechanism of the hyperfine interaction in these systems. Muonium addition to the ring systems of these compounds was also observed and the hyperfine frequencies assigned and discussed.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Physical and Analytical Chemistry
Depositing User: Rachel Smith
Date Deposited: 09 May 2011 12:41
Last Modified: 21 Aug 2018 10:31
URI: https://ueaeprints.uea.ac.uk/id/eprint/29786
DOI:

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