The detection of the electronic spectrum of FeCl2 in the gas phase

Ashworth, Stephen H., Hodges, Philip J. and Brown, John M. (2002) The detection of the electronic spectrum of FeCl2 in the gas phase. Physical Chemistry Chemical Physics, 4 (24). pp. 5923-5924. ISSN 1463-9084

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Abstract

Transition metal dihalides are prototypical molecules which provide an excellent test of ligand-field and higher level theories. Most of them have open-shell electronic structures and complicated electronic spectra. Although they have been studied for a long time,1,2 it is only in recent years that definitive studies have been carried out through the recording of gasphase spectra at rotational resolution.3,4 FeCl2 is one member of this group. In this communication, we report the first high resolution study of this species.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Physical and Analytical Chemistry
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Depositing User: Rachel Smith
Date Deposited: 18 Apr 2011 11:06
Last Modified: 25 Jul 2018 07:20
URI: https://ueaeprints.uea.ac.uk/id/eprint/29515
DOI: 10.1039/b209523h

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