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ToolsAbiman, Poobalasingam, Wildgoose, Gregory G., Xiao, Lei and Compton, Richard G. (2008) The convenient determination of palladium at a solid electrode via adsorptive stripping voltammetry at a glassy carbon electrode modified with a random array of mercury nanodroplets. Electroanalysis, 20 (14). pp. 1607-1609. ISSN 1521-4109
Full text not available from this repository.Abstract
The detection of palladium using adsorptive stripping voltammetry reported by Wang et al. (J. Wang, K. Varughese Anal. Chim. Acta 1987, 199, 185 [3]) at a hanging mercury drop electrode is extended to a more convenient solid electrode. To this end a random array of 3.5×108 mercury nanodroplets per cm2 (65 nm average diameter) was electrodeposited on a glassy carbon substrate. Adsorptive stripping voltammetry was performed using 2×10-4 M dimethylglyoxime as a chelating agent for the Pd(II) ion, with accumulation at -0.20 V vs. SCE for 120 s and a linear detection range of 5–150 µM was determined with a limit of detection of 1.6 µM.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Physical and Analytical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) |
| Depositing User: | Rachel Smith |
| Date Deposited: | 29 Mar 2011 16:02 |
| Last Modified: | 16 Jan 2023 16:30 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/27492 |
| DOI: | 10.1002/elan.200804244 |
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