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Rijkenberg, Micha J. A., Powell, Claire F., Dall'Osto, Manuel, Nielsdottir, Maria C., Patey, Matthew D., Hill, Polly G., Baker, Alex R. 
ORCID: https://orcid.org/0000-0002-8365-8953, Jickells, Tim D., Harrison, Roy M. and Achterberg, Eric P.
(2008)
Changes in iron speciation following a Saharan dust event in the tropical North Atlantic Ocean.
Marine Chemistry, 110 (1-2).
pp. 56-67.
Abstract
Concentrations of dissolved iron (DFe) and Fe-binding ligands were determined in the tropical Northeast Atlantic Ocean (12–30°N, 21–29°W) as part of the UK-SOLAS (Surface Ocean Lower Atmosphere Study) cruise Poseidon 332 (P332) in January–February 2006. The surface water DFe concentrations varied between 0.1 and 0.4 nM with an average of 0.22 ± 0.05 nM (n = 159). The surface water concentrations of total Fe-binding ligands varied between 0.82 and 1.46 nM with an average of 1.11 ± 0.14 nM (n = 33). The concentration of uncomplexed Fe-binding ligands varied between 0.64 and 1.35 nM with an average of 0.90 ± 0.14 nM (n = 33). Thus, on average 81% of the total Fe-binding ligand concentration was uncomplexed. The average logarithmic conditional stability constant of the pool of Fe-binding ligands was 22.85 ± 0.38 with respect to Fe3+ (n = 33). A transect (12°N, 26°W to 16°N, 25.3°W) was sailed during a small Saharan dust event and repeated a week later. Following the dust event, the concentration of DFe increased from 0.20 ± 0.026 nM (n = 125) to 0.25 ± 0.028 (n = 17) and the concentration of free Fe-binding ligands decreased from 1.15 ± 0.15 (n = 4) to 0.89 ± 0.10 (n = 4) nM. Furthermore, the logarithmic stability constants of the Fe-binding ligands south of the Cape Verde islands were distinctively lower than north of the islands. The absence of a change in the logarithmic stability constant after the dust event south of the Cape Verde islands suggests that there was no significant atmospheric input of new Fe-binding ligands during this dust event.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Environmental Sciences University of East Anglia Research Groups/Centres > Theme - ClimateUEA |
| UEA Research Groups: | Faculty of Science > Research Groups > Centre for Ocean and Atmospheric Sciences |
| Depositing User: | Rosie Cullington |
| Date Deposited: | 26 Feb 2011 11:27 |
| Last Modified: | 11 Mar 2024 00:53 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/24803 |
| DOI: | 10.1016/j.marchem.2008.02.006 |
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