Hybrid catalysts: the synthesis, structure and ethene polymerisation activity of (salicylaldiminato)(pyrrolylaldiminato) titanium complexes

Pennington, DA, Coles, SJ, Hursthouse, MB, Bochmann, M and Lancaster, SJ (2005) Hybrid catalysts: the synthesis, structure and ethene polymerisation activity of (salicylaldiminato)(pyrrolylaldiminato) titanium complexes. Chemical Communications (25). pp. 3150-3152. ISSN 1364-548X

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Abstract

The mono(salicylaldiminato) complexes Ti{3-tBu-2-(O)C6H3CH==N(R)}Cl3(THF) (where R = C6H5, C6F5) react with the metallated pyrrolylaldiminato ligand, K[2-(C6H5NCH)C4H3N], to afford the first examples of hybrid salicylaldiminato-ligated octahedral titanium complexes; the pre-catalysts give from very high to extremely high ethene polymerisation productivities when activated with MAO.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
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Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 18 Sep 2018 10:31
URI: https://ueaeprints.uea.ac.uk/id/eprint/10512
DOI: 10.1039/b504113a

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