Hybrid catalysts: the synthesis, structure and ethene polymerisation activity of (salicylaldiminato)(pyrrolylaldiminato) titanium complexes

Pennington, Dale A., Coles, Simon J., Hursthouse, Michael B., Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 and Lancaster, Simon J. (2005) Hybrid catalysts: the synthesis, structure and ethene polymerisation activity of (salicylaldiminato)(pyrrolylaldiminato) titanium complexes. Chemical Communications (25). pp. 3150-3152. ISSN 1364-548X

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Abstract

The mono(salicylaldiminato) complexes Ti{3-tBu-2-(O)C6H3CH==N(R)}Cl3(THF) (where R = C6H5, C6F5) react with the metallated pyrrolylaldiminato ligand, K[2-(C6H5NCH)C4H3N], to afford the first examples of hybrid salicylaldiminato-ligated octahedral titanium complexes; the pre-catalysts give from very high to extremely high ethene polymerisation productivities when activated with MAO.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	01 Mar 2023 16:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10512
DOI:	10.1039/b504113a

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