Synthesis and catalytic activity of binuclear titanium imido complexes

Said, M, Hughes, DL and Bochmann, M (2004) Synthesis and catalytic activity of binuclear titanium imido complexes. Dalton Transactions (3). pp. 359-360.

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Abstract

Treatment of the N–P ligand ArPN(SiMe3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(µ-NArP)]2(ArP=m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR2 functional groups.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
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Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 25 Jul 2018 06:45
URI: https://ueaeprints.uea.ac.uk/id/eprint/10500
DOI: 10.1039/b315711c

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