New Bulky Allyl Complexes of Lanthanide Metals: Role of Alkali-Metal Cations in Controlling Solid-State and Solution Assemblies in Precatalysts

Woodman, TJ, Schormann, M, Hughes, DL and Bochmann, M (2003) New Bulky Allyl Complexes of Lanthanide Metals: Role of Alkali-Metal Cations in Controlling Solid-State and Solution Assemblies in Precatalysts. Organometallics, 22 (15). pp. 3028-3030.

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Abstract

The reaction of the bulky allyl anion [1,3-C3H3(SiMe3)2]- with SmI2(THF)2 gives the allyl-bridged dimer [Sm(C3H3(SiMe3)2)3{µ-K(THF)2}]2, the first structurally authenticated Sm(II) allyl complex. The compound is a highly effective single-component catalyst for the polymerization of methyl methacrylate and e-caprolactone.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
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Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 25 Jul 2018 07:01
URI: https://ueaeprints.uea.ac.uk/id/eprint/10493
DOI: 10.1021/om030283e

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